| Sulfone-containing covalent organic frameworks for photocatalytic hydrogen evolution from water |
156 |
| Organic synthesis provides opportunities to transform drug discovery |
145 |
| High phase-purity 1T'-MoS2- and 1T'-MoSe2- layered crystals |
138 |
| Dopant-induced electron localization drives CO2 reduction to C-2 hydrocarbons |
114 |
| Towards the online computer-aided design of catalytic pockets |
111 |
| Few-layer graphdiyne doped with sp-hybridized nitrogen atoms at acetylenic sites for oxygen reduction electrocatalysis |
98 |
| Copper atom-pair catalyst anchored on alloy nanowires for selective and efficient electrochemical reduction of CO2 |
87 |
| Chemically stable polyarylether-based covalent organic frameworks |
82 |
| Pt/Cu single-atom alloys as coke-resistant catalysts for efficient C-H activation |
81 |
| Molecular spins for quantum computation |
81 |
| Reversible calcium alloying enables a practical room-temperature rechargeable calcium-ion battery with a high discharge voltage |
79 |
| Oxygen redox chemistry without excess alkali-metal ions in Na-2/3[Mg0.28Mn0.72]O-2 |
77 |
| Theory-driven design of high-valence metal sites for water oxidation confirmed using in situ soft X-ray absorption |
73 |
| Prevention of dendrite growth and volume expansion to give high-performance aprotic bimetallic Li-Na alloy-O-2 batteries |
70 |
| Imaging defects and their evolution in a metal-organic framework at sub-unit-cell resolution |
63 |
| I-motif DNA structures are formed in the nuclei of human cells |
62 |
| Closed-loop recycling of plastics enabled by dynamic covalent diketoenamine bonds |
62 |
| Polyoxometalate electrocatalysts based on earth-abundant metals for efficient water oxidation in acidic media |
60 |
| Artificial muscle-like function from hierarchical supramolecular assembly of photoresponsive molecular motors |
59 |
| An artificial interphase enables reversible magnesium chemistry in carbonate electrolytes |
56 |
| N-heterocyclic carbene-functionalized magic-number gold nanoclusters |
55 |
| Microporous membranes comprising conjugated polymers with rigid backbones enable ultrafast organic-solvent nanofiltration |
53 |
| Organocatalytic asymmetric arylation of indoles enabled by azo groups |
50 |
| Spontaneous doping of the basal plane of MoS2 single layers through oxygen substitution under ambient conditions |
50 |
| Decarboxylative alkylation for site-selective bioconjugation of native proteins via oxidation potentials |
50 |
| Free-atom-like d states in single-atom alloy catalysts |
49 |
| A fluorescent membrane tension probe |
48 |
| Identifying the components of the solid-electrolyte interphase in Li-ion batteries |
47 |
| Identification of the strong Bronsted acid site in a metal-organic framework solid acid catalyst |
45 |
| Self-assembly of polyhedral metal-organic framework particles into three-dimensional ordered superstructures |
44 |
| Practical and regioselective amination of arenes using alkyl amines |
44 |
| Harvesting multiple electron-hole pairs generated through plasmonic excitation of Au nanoparticles |
44 |
| Crystal phase-based epitaxial growth of hybrid noble metal nanostructures on 4H/fcc Au nanowires |
43 |
| Atomic resolution of structural changes in elastic crystals of copper(II) acetylacetonate |
43 |
| Molecular engineering of organic-inorganic hybrid perovskites quantum wells |
41 |
| Engineered modular biomaterial logic gates for environmentally triggered therapeutic delivery |
41 |
| Targeted photoredox catalysis in cancer cells |
41 |
| On-water surface synthesis of crystalline, few-layer two-dimensional polymers assisted by surfactant monolayers |
41 |
| Concerted nucleophilic aromatic substitutions |
40 |
| Liquid-liquid phase separation during amphiphilic self-assembly |
39 |
| A biomimetic receptor for glucose |
38 |
| Structure-performance descriptors and the role of Lewis acidity in the methanol-to-propylene process |
38 |
| Non-chemisorbed gold-sulfur binding prevails in self-assembled monolayers |
37 |
| Structure-based inhibitors of tau aggregation |
37 |
| Hydroxide diffuses slower than hydronium in water because its solvated structure inhibits correlated proton transfer |
37 |
| Site-selective photoinduced cleavage and profiling of DNA by chiral semiconductor nanoparticles |
35 |
| Stereoselective synthesis of a composite knot with nine crossings |
35 |
| Manganese-catalysed benzylic C(sp(3))-H amination for late-stage functionalization |
35 |
| Shear-induced assembly of a transient yet highly stretchable hydrogel based on pseudopolyrotaxanes |
35 |
| The photochemical ring-opening of 3-cyclohexadiene imaged by ultrafast electron diffraction |
34 |
| Identification and characterization of diverse coherences in the Fenna-Matthews-Olson complex |
34 |
| Enrichment-triggered prodrug activation demonstrated through mitochondria-targeted delivery of doxorubicin and carbon monoxide |
33 |
| Controlling Pd(IV) reductive elimination pathways enables Pd(II)-catalysed enantioselective C(sp(3))-H fluorination |
33 |
| Diverse compounds from pleuromutilin lead to a thioredoxin inhibitor and inducer of ferroptosis |
33 |
| Regio- and diastereoselective intermolecular [2+2] cycloadditions photocatalysed by quantum dots |
32 |
| Hierarchical organization of perylene bisimides and polyoxometalates for photo-assisted water oxidation |
32 |
| A general asymmetric copper-catalysed Sonogashira C(sp(3))-C(sp) coupling |
32 |
| Amino-acid-encoded biocatalytic self-assembly enables the formation of transient conducting nanostructures |
32 |
| Asymmetric transfer hydrogenation by synthetic catalysts in cancer cells |
31 |
| Heteromultivalent peptide recognition by co-assembly of cyclodextrin and calixarene amphiphiles enables inhibition of amyloid fibrillation |
31 |
| An integrated native mass spectrometry and top-down proteomics method that connects sequence to structure and function of macromolecular complexes |
30 |
| Direct alpha-C-H bond functionalization of unprotected cyclic amines |
30 |
| Thermally activated delayed photoluminescence from pyrenyl-functionalized CdSe quantum dots |
30 |
| Formation of the layered conductive magnet CrCl2(pyrazine)(2) through redox-active coordination chemistry |
30 |
| Second-generation DNA-templated macrocycle libraries for the discovery of bioactive small molecules |
30 |
| Hydrolytic stability in hemilabile metal-organic frameworks |
29 |
| Controllable catalytic difluorocarbene transfer enables access to diversified fluoroalkylated arenes |
29 |
| Cholesterol catalyses A beta 42 aggregation through a heterogeneous nucleation pathway in the presence of lipid membranes |
29 |
| Iridium-catalysed arylation of C-H bonds enabled by oxidatively induced reductive elimination |
28 |
| Collaborative routes to clarifying the murky waters of aqueous supramolecular chemistry |
28 |
| Highly reduced and protonated aqueous solutions of [P2W18O62](6-) for on-demand hydrogen generation and energy storage |
28 |
| The energy-transfer-enabled biocompatible disulfide-ene reaction |
28 |
| Maleimide-thiol adducts stabilized through stretching |
27 |
| Catalytic dehydrogenative decarboxyolefination of carboxylic acids |
27 |
| Complementary site-selectivity in arene functionalization enabled by overcoming the ortho constraint in palladium/norbornene catalysis |
27 |
| Identification of a Frank-Kasper Z phase from shape amphiphile self-assembly |
27 |
| Isoreticular two-dimensional magnetic coordination polymers prepared through pre-synthetic ligand functionalization |
27 |
| Direct alpha-alkylation of primary aliphatic amines enabled by CO2 and electrostatics |
27 |
| Signalling and differentiation in emulsion-based multi-compartmentalized in vitro gene circuits |
26 |
| Iron(II) coordination complexes with panchromatic absorption and nanosecond charge-transfer excited state lifetimes |
25 |
| Fast galvanic lithium corrosion involving a Kirkendall-type mechanism |
25 |
| Substrate-driven chemotactic assembly in an enzyme cascade |
25 |
| An enzymatic platform for the asymmetric amination of primary, secondary and tertiary C(sp(3))-H bonds |
25 |
| Photochemical generation of radicals from alkyl electrophiles using a nucleophilic organic catalyst |
24 |
| Programmable autonomous synthesis of single-stranded DNA |
24 |
| Phosphorylation, oligomerization and self-assembly in water under potential prebiotic conditions |
24 |
| Morphology tuning of inorganic nanomaterials grown by precipitation through control of electrolytic dissociation and supersaturation |
24 |
| Mesopolymer synthesis by ligand-modulated direct arylation polycondensation towards n-type and ambipolar conjugated systems |
24 |
| Design of catalysts for site-selective and enantioselective functionalization of non-activated primary C-H bonds |
24 |
| A general strategy for synthesis of cyclophane-braced peptide macrocycles via palladium-catalysed intramolecular sp(3) C-H arylation |
24 |
| A designer enzyme for hydrazone and oxime formation featuring an unnatural catalytic aniline residue |
24 |
| Endothermic singlet fission is hindered by excimer formation |
24 |
| Mutually orthogonal pyrrolysyl-tRNA synthetase/tRNA pairs |
23 |
| Enzyme-powered motility in buoyant organoclay/DNA protocells |
23 |
| Cyclization of peptides with two chemical bridges affords large scaffold diversities |
23 |
| Robust gold nanorods stabilized by bidentate N-heterocyclic-carbene-thiolate ligands |
23 |
| Ring-through-ring molecular shuttling in a saturated [3]rotaxane |
23 |
| Dynamic actuation of glassy polymersomes through isomerization of a single azobenzene unit at the block copolymer interface |
23 |
| Chromophore twisting in the excited state of a photoswitchable fluorescent protein captured by time-resolved serial femtosecond crystallography |
23 |
| Autonomous dynamic control of DNA nanostructure self-assembly |
23 |
| Carbopalladation of C-C sigma-bonds enabled by strained boronate complexes |
23 |
| 5-Formylcytosine organizes nucleosomes and forms Schiff base interactions with histones in mouse embryonic stem cells |
22 |
| Coherent wavepackets in the Fenna-Matthews-Olson complex are robust to excitonic-structure perturbations caused by mutagenesis |
22 |
| Formation of carbon-nitrogen bonds in carbon monoxide electrolysis |
22 |
| An automated platform for the enzyme-mediated assembly of complex oligosaccharides |
22 |
| Thiophene and its sulfur inhibit indenoindenodibenzothiophene diradicals from low-energy lying thermal triplets |
21 |
| Tailored silyl ether monomers enable backbone-degradable polynorbornene-based linear, bottlebrush and star copolymers through ROMP |
21 |
| Cyclometallated ruthenium catalyst enables late-stage directed arylation of pharmaceuticals |
21 |
| Catalytic promiscuity enabled by photoredox catalysis in nicotinamide-dependent oxidoreductases |
21 |
| De novo design and engineering of non-ribosomal peptide synthetases |
21 |
| Polyyne formation via skeletal rearrangement induced by atomic manipulation |
21 |
| Dual chemical probes enable quantitative system-wide analysis of protein prenylation and prenylation dynamics |
20 |
| From alkylarenes to anilines via site-directed carbon-carbon amination |
20 |
| Ultra-fast intramolecular singlet fission to persistent multiexcitons by molecular design |
20 |
| A nucleophilic gold complex |
20 |
| Metathesis-active ligands enable a catalytic functional group metathesis between aroyl chlorides and aryl iodides |
20 |
| Strategies for microbial synthesis of high-value phytochemicals |
20 |
| Single-atom gold oxo-clusters prepared in alkaline solutions catalyse the heterogeneous methanol self-coupling reactions |
19 |
| The role of sugar-backbone heterogeneity and chimeras in the simultaneous emergence of RNA and DNA |
19 |
| The mechanisms of boronate ester formation and fluorescent turn-on in ortho-aminomethylphenylboronic acids |
19 |
| The role of bridging ligands in dinitrogen reduction and functionalization by uranium multimetallic complexes |
19 |
| Photosensitized oxidative addition to gold(I) enables alkynylative cyclization of o-alkylnylphenols with iodoalkynes |
19 |
| The formation of all-cis-(multi)fluorinated piperidines by a dearomatization-hydrogenation process |
19 |
| Cold quantum-controlled rotationally inelastic scattering of HD with H-2 and D-2 reveals collisional partner reorientation |
19 |
| Radical polymerization inside living cells |
18 |
| Catalytic activation of unstrained C(aryl)-C(aryl) bonds in 2 '-biphenols |
18 |
| Biocatalytic site- and enantioselective oxidative dearomatization of phenols |
18 |
| Kinetic modulation of graphene growth by fluorine through spatially confined decomposition of metal fluorides |
18 |
| Distinct thermodynamic signatures of oligomer generation in the aggregation of the amyloid-beta peptide |
18 |
| Modification and de novo design of non-ribosomal peptide synthetases using specific assembly points within condensation domains |
18 |
| Expedited mapping of the ligandable proteome using fully functionalized enantiomeric probe pairs |
18 |
| Modular and regioselective synthesis of all-carbon tetrasubstituted olefins enabled by an alkenyl Catellani reaction |
18 |
| Direct knock-on of desolvated ions governs strict ion selectivity in K+ channels |
17 |
| Braiding, branching and chiral amplification of nanofibres in supramolecular gels |
17 |
| Evolving artificial metalloenzymes via random mutagenesis |
17 |
| Palladium-catalysed anti-Markovnikov selective oxidative amination |
17 |
| Ribosomal synthesis and folding of peptide-helical aromatic foldamer hybrids |
17 |
| Versatile protein recognition by the encoded display of multiple chemical elements on a constant macrocyclic scaffold |
17 |
| Genetically encoded lipid-polypeptide hybrid biomaterials that exhibit temperature-triggered hierarchical self-assembly |
17 |
| De novo macrocyclic peptides that specifically modulate Lys48-linked ubiquitin chains |
17 |
| Isotherms of individual pores by gas adsorption crystallography |
17 |
| Supercharging enables organized assembly of synthetic biomolecules |
17 |
| Reversing conventional site-selectivity in C(sp(3))-H bond activation |
16 |
| Photodriven quantum teleportation of an electron spin state in a covalent donor-acceptor-radical system |
16 |
| A chemoselective strategy for late-stage functionalization of complex small molecules with polypeptides and proteins |
16 |
| Quantum-state-controlled channel branching in cold Ne(P-3(2))+Ar chemi-ionization |
16 |
| DNA-imprinted polymer nanoparticles with monodispersity and prescribed DNA-strand patterns |
16 |
| Highly responsive nature of porous coordination polymer surfaces imaged by in situ atomic force microscopy |
16 |
| Single-cell mRNA cytometry via sequence-specific nanoparticle clustering and trapping |
16 |
| Efficient and stereodivergent synthesis of unsaturated acyclic fragments bearing contiguous stereogenic elements |
16 |
| Diels-Alder cycloadditions of strained azacyclic allenes |
15 |
| Chromopynones are pseudo natural product glucose uptake inhibitors targeting glucose transporters GLUT-1 and-3 |
15 |
| A marine viral halogenase that iodinates diverse substrates |
15 |
| The role of uranium-arene bonding in H2O reduction catalysis |
15 |
| Fungal indole alkaloid biogenesis through evolution of a bifunctional reductase/Diels-Alderase |
15 |
| Evolution of sequence-defined highly functionalized nucleic acid polymers |
15 |
| Enantioselective construction of remote tertiary carbon-fluorine bonds |
15 |
| Scattering resonances in bimolecular collisions between NO radicals and H-2 challenge the theoretical gold standard |
15 |
| Observation of the adsorption and desorption of vibrationally excited molecules on a metal surface |
15 |
| Fragment-derived inhibitors of human N-myristoyltransferase block capsid assembly and replication of the common cold virus |
15 |
| Optimization of the facet structure of transition-metal catalysts applied to the oxygen reduction reaction |
15 |
| The reductive C3 functionalization of pyridinium and quinolinium salts through iridium-catalysed interrupted transfer hydrogenation |
15 |
| Tracing the 'ninth sulfur' of the nitrogenase cofactor via a semi-synthetic approach |
15 |
| Mechanism-based enhancement of scope and enantioselectivity for reactions involving a copper-substituted stereogenic carbon centre |
15 |
| Predicting DNA hybridization kinetics from sequence |
15 |
| Chemoselective methylene oxidation in aromatic molecules |
15 |
| Cavitation energies can outperform dispersion interactions |
14 |
| On-surface synthesis and characterization of individual polyacetylene chains |
14 |
| Super-resolution imaging of non-fluorescent reactions via competition |
14 |
| Experimental and computational evidence of halogen bonds involving astatine |
14 |
| Chemical evolution of atmospheric organic carbon over multiple generations of oxidation |
14 |
| Isolation, synthesis and bioactivity studies of phomactin terpenoids |
14 |
| Narrow-band single-photon emission through selective aryl functionalization of zigzag carbon nanotubes |
14 |
| Evaluating differences in the active-site electronics of supported Au nanoparticle catalysts using Hammett and DFT studies |
14 |
| Accelerating proton-coupled electron transfer of metal hydrides in catalyst model reactions |
13 |
| Ion-mediated hydrogen-bond rearrangement through tunnelling in the iodide-dihydrate complex |
13 |
| Transferring the entatic-state principle to copper photochemistry |
13 |
| Visualizing pore architecture and molecular transport boundaries in catalyst bodies with fluorescent nanoprobes |
13 |
| Electronic landscape of the P-cluster of nitrogenase as revealed through many-electron quantum wavefunction simulations |
13 |
| A genetically encoded photosensitizer protein facilitates the rational design of a miniature photocatalytic CO2-reducing enzyme |
13 |
| Evidence for a vibrational phase-dependent isotope effect on the photochemistry of vision |
13 |
| Rapamycin-inspired macrocycles with new target specificity |
13 |
| Dynamic self-correcting nucleophilic aromatic substitution |
13 |
| A synthetic genetic polymer with an uncharged backbone chemistry based on alkyl phosphonate nucleic acids |
12 |
| Late-stage chemoselective functional-group manipulation of bioactive natural products with super-electrophilic silylium ions |
12 |
| Relativistic quantum chemical calculations show that the uranium molecule U-2 has a quadruple bond |
12 |
| Mining the cellular inventory of pyridoxal phosphate-dependent enzymes with functionalized cofactor mimics |
12 |
| Carbohydrate stabilization extends the kinetic limits of chemical polysaccharide depolymerization |
12 |
| Ultrafast X-ray scattering reveals vibrational coherence following Rydberg excitation |
12 |
| Energy threshold for chiral symmetry breaking in molecular self-replication |
12 |
| Computational advances in combating colloidal aggregation in drug discovery |
12 |
| E- and Z di- and tri-substituted alkenyl nitriles through catalytic cross-metathesis |
12 |
| Streamlining the chemoenzymatic synthesis of complex N-glycans by a stop and go strategy |
12 |
| Light-driven molecular trap enables bidirectional manipulation of dynamic covalent systems |
12 |
| A molecular multi-gene classifier for disease diagnostics |
12 |
| Two-dimensional Na-Cl crystals of unconventional stoichiometries on graphene surface from dilute solution at ambient conditions |
12 |
| The domino hexadehydro-Diels-Alder reaction transforms polyynes to benzynes to naphthynes to anthracynes to tetracynes (and beyond?) |
11 |
| Broadband 2D IR spectroscopy reveals dominant asymmetric H5O2+ proton hydration structures in acid solutions |
11 |
| Activation of diverse carbon-heteroatom and carbon-carbon bonds via palladium(II)-catalysed beta-X elimination |
11 |
| Capture of nitrogen dioxide and conversion to nitric acid in a porous metal-organic framework |
11 |
