Chem

Chem

化学

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文章名称 引用次数
Nitrogen Fixation by Ru Single-Atom Electrocatalytic Reduction 168
Nanostructured Conversion-type Anode Materials for Advanced Lithium-Ion Batteries 131
Graphene Defects Trap Atomic Ni Species for Hydrogen and Oxygen Evolution Reactions 128
Recent Advances in Energy Chemistry between Solid-State Electrolyte and Safe Lithium-Metal Anodes 127
Electrochemical Oxidative Cross-coupling with Hydrogen Evolution: A Green and Sustainable Way for Bond Formation 125
Highly Fluorinated Interphases Enable High-Voltage Li-Metal Batteries 122
Surface and Heterointerface Engineering of 2D MXenes and Their Nanocomposites: Insights into Electro- and Photocatalysis 109
Transient Directing Groups for Transformative C-H Activation by Synergistic Metal Catalysis 100
Surface and Interface Engineering in Copper-Based Bimetallic Materials for Selective CO2 Electroreduction 93
Metal-Organic-Framework-Based Single-Atom Catalysts for Energy Applications 92
Localized High-Concentration Sulfone Electrolytes for High-Efficiency Lithium-Metal Batteries 85
Metal Sulfides as Excellent Co-catalysts for H2O2 Decomposition in Advanced Oxidation Processes 83
Polymer Electrolytes for Lithium-Based Batteries: Advances and Prospects 83
Design Strategies toward Enhancing the Performance of Organic Electrode Materials in Metal-Ion Batteries 81
Practical Challenges and Future Perspectives of All-Solid-State Lithium-Metal Batteries 80
2D sp(2) Carbon-Conjugated Covalent Organic Frameworks for Photocatalytic Hydrogen Production from Water 79
Review of Metal Catalysts for Oxygen Reduction Reaction: From Nanoscale Engineering to Atomic Design 78
N-Doped Graphitized Carbon Nanohorns as a Forefront Electrocatalyst in Highly Selective O-2 Reduction to H2O2 61
Progress toward Commercial Application of Electrochemical Carbon Dioxide Reduction 60
Lewis-Acid-Catalyzed Interfacial Polymerization of Covalent Organic Framework Films 60
Room-Temperature Methane Conversion by Graphene-Confined Single Iron Atoms 59
Covalent Organic Frameworks Linked by Amine Bonding for Concerted Electrochemical Reduction of CO2 59
Charge-Redistribution-Enhanced Nanocrystalline Ru@IrOx Electrocatalysts for Oxygen Evolution in Acidic Media 59
Metal-Organic Frameworks for Chemiresistive Sensors 55
The Role of Defect Sites in Nanomaterials for Electrocatalytic Energy Conversion 54
Facile Synthesis of Multi-shelled ZnS-CdS Cages with Enhanced Photoelectrochemical Performance for Solar Energy Conversion 51
Molecular-Scale Porous Materials Based on Pillar[n]arenes 51
Sigma-Hole Interactions in Anion Recognition 50
Metal-Organic Frameworks for the Capture of Trace Aromatic Volatile Organic Compounds 50
Room-Temperature Molten Salt for Facile Fabrication of Efficient and Stable Perovskite Solar Cells in Ambient Air 50
The Chemistry of CO: Carbonylation 50
Hierarchically Engineered Mesoporous Metal-Organic Frameworks toward Cell-free Immobilized Enzyme Systems 49
Insight into High-Performance Conjugated Polymers for Organic Field-Effect Transistors 49
A Defect-Driven Metal-free Electrocatalyst for Oxygen Reduction in Acidic Electrolyte 48
In Situ Generation of Bifunctional, Efficient Fe-Based Catalysts from Mackinawite Iron Sulfide for Water Splitting 47
Multi-Stimuli-Responsive Polymer Particles, Films, and Hydrogels for Drug Delivery 46
Catalytic Production of Value-Added Chemicals and Liquid Fuels from Lignocellulosic Biomass 46
Photoelectrochemical Synthesis of Ammonia on the Aerophilic-Hydrophilic Heterostructure with 37.8% Efficiency 46
Electrocatalytic Reduction of Nitrogen: From Haber-Bosch to Ammonia Artificial Leaf 45
Nanoscale Metal-Organic Framework Mediates Radical Therapy to Enhance Cancer Immunotherapy 45
Scalable and Sustainable Approach toward Highly Compressible, Anisotropic, Lamellar Carbon Sponge 45
Reconstructed Orthorhombic V2O5 Polyhedra for Fast Ion Diffusion in K-Ion Batteries 43
Precisely Tuning the Number of Fe Atoms in Clusters on N-Doped Carbon toward Acidic Oxygen Reduction Reaction 42
High-Concentration Single Atomic Pt Sites on Hollow CuSx for Selective O-2 Reduction to H2O2 in Acid Solution 42
Iridium Single-Atom Catalyst Performing a Quasi-homogeneous Hydrogenation Transformation of CO2 to Formate 41
Reticular Chemistry in Action: A Hydrolytically Stable MOF Capturing Twice Its Weight in Adsorbed Water 40
Regulating the Charge and Spin Ordering of Two-Dimensional Ultrathin Solids for Electrocatalytic Water Splitting 39
Metal Surface and Interface Energy Electrocatalysis: Fundamentals, Performance Engineering, and Opportunities 39
Alkali Metal Anodes for Rechargeable Batteries 37
Understanding the Nature of Ammonia Treatment to Synthesize Oxygen Vacancy-Enriched Transition Metal Oxides 37
Tailoring pi-Conjugated Systems: From pi-pi Stacking to High-Rate-Performance Organic Cathodes 37
Self-Standing Hierarchical P/CNTs@rGO with Unprecedented Capacity and Stability for Lithium and Sodium Storage 36
Polymerization-Enhanced Photosensitization 35
Continuous Grain-Boundary Functionalization for High-Efficiency Perovskite Solar Cells with Exceptional Stability 35
New Horizons of Photocatalytic Fluoromethylative Difunctionalization of Alkenes 35
Quasi-MOF: Exposing Inorganic Nodes to Guest Metal Nanoparticles for Drastically Enhanced Catalytic Activity 34
Edge-Functionalized g-C3N4 Nanosheets as a Highly Efficient Metal-free Photocatalyst for Safe Drinking Water 33
Enhanced Reactivity by Torsional Strain of Cyclic Diaryliodonium in Cu-Catalyzed Enantioselective Ring-Opening Reaction 33
Efficient Syntheses of Diverse, Medicinally Relevant Targets Planned by Computer and Executed in the Laboratory 33
Triboluminescence: Recalling Interest and New Aspects 32
A Visible and Near-Infrared, Dual-Channel Fluorescence-On Probe for Selectively Tracking Mitochondrial Glutathione 32
Reversible Mg-Ion Insertion in a Metastable One-Dimensional Polymorph of V2O5 32
Palladium-Catalyzed C(sp(3))-H Bond Functionalization of Aliphatic Amines 32
Chirality Effects on Peptide Self-Assembly Unraveled from Molecules to Materials 31
Integrating Superwettability within Covalent Organic Frameworks for Functional Coating 31
Vanadium Oxide Pillared by Interlayer Mg2+ Ions and Water as Ultralong-Life Cathodes for Magnesium-Ion Batteries 31
Transition-Metal-Catalyzed Intramolecular Nucleophilic Addition of Carbonyl Groups to Alkynes 30
Remote sp(3) C-H Amination of Alkenes with Nitroarenes 30
Horizontal Centripetal Plating in the Patterned Voids of Li/Graphene Composites for Stable Lithium-Metal Anodes 30
G-Quadruplex: A Regulator of Gene Expression and Its Chemical Targeting 29
Breaking the Limit of Lignin Monomer Production via Cleavage of Interunit Carbon-Carbon Linkages 29
Achieving High Energy Density through Increasing the Output Voltage: A Highly Reversible 5.3 V Battery 29
Understanding Thermodynamic and Kinetic Contributions in Expanding the Stability Window of Aqueous Electrolytes 29
Polymer Mechanochemistry: Manufacturing Is Now a Force to Be Reckoned With 29
Xenon Gas Separation and Storage Using Metal-Organic Frameworks 28
Stabilizing a High-Energy-Density Rechargeable Sodium Battery with a Solid Electrolyte 28
Toward Infinitely Recyclable Plastics Derived from Renewable Cyclic Esters 28
DNA-Sequence-Encoded Rolling Circle Amplicon for Single-Cell RNA Imaging 28
A Fully Sodiated NaVOPO4 with Layered Structure for High-Voltage and Long-Lifespan Sodium-Ion Batteries 28
Stabilization of a High-Capacity and High-Power Nickel-Based Cathode for Li-Ion Batteries 28
Calcium-Overload-Mediated Tumor Therapy by Calcium Peroxide Nanoparticles 28
Improving the Acidic Stability of Zeolitic Imidazolate Frameworks by Biofunctional Molecules 27
Function-Oriented Engineering of Metal-Based Nanohybrids for Photoredox Catalysis: Exerting Plasmonic Effect and Beyond 27
DNA Nanostructures at the Interface with Biology 27
Enzyme-Instructed Peptide Assemblies Selectively Inhibit Bone Tumors 26
Metallic Transition-Metal Dichalcogenide Nanocatalysts for Energy Conversion 26
A Long-Lifetime All-Organic Aqueous Flow Battery Utilizing TMAP-TEMPO Radical 26
Material Chemistry of Two-Dimensional Inorganic Nanosheets in Cancer Theranostics 26
Pathways to Widespread Applications: Development of Redox Flow Batteries Based on New Chemistries 25
Synthesis of Armchair and Chiral Carbon Nanobelts 25
Cobalt-Catalyzed Asymmetric Synthesis of gem-Bis(silyl)alkanes by Double Hydrosilylation of Aliphatic Terminal Alkynes 25
Copper-Catalyzed Asymmetric Defluoroborylation of 1-(Trifluoromethyl)Alkenes 25
Current Mechanistic Understanding of Surface Reactions over Water-Splitting Photocatalysts 25
Intermediate Modulation on Noble Metal Hybridized to 2D Metal-Organic Framework for Accelerated Water Electrocatalysis 24
Superionic Diffusion through Frustrated Energy Landscape 24
Combining Quinone Cathode and Ionic Liquid Electrolyte for Organic Sodium-Ion Batteries 24
Muscle-like Artificial Molecular Actuators for Nanoparticles 24
Insights into the Improved High-Voltage Performance of Li-Incorporated Layered Oxide Cathodes for Sodium-Ion Batteries 24
Application of Palladium-Catalyzed C(sp(2))-H Bond Arylation to the Synthesis of Polycyclic (Hetero)Aromatics 24
Ultra-Small Face-Centered-Cubic Ru Nanoparticles Confined within a Porous Coordination Cage for Dehydrogenation 23
Thiol Treatment Creates Selective Palladium Catalysts for Semihydrogenation of Internal Alkynes 21
Evidence for Charge-Transfer Mediation in the Primary Events of Singlet Fission in a Weakly Coupled Pentacene Dimer 21
Construction of Single-Crystalline Prussian Blue Analog Hollow Nanostructures with Tailorable Topologies 21
Leaf-Inspired Self-Healing Polymers 21
Distinctive Two-Step Intercalation of Sr2+ into a Coordination Polymer with Record High Sr-90 Uptake Capabilities 21
14.1% Efficient Monolithically Integrated Solar Flow Battery 21
Electrolyzer Design for Flexible Decoupled Water Splitting and Organic Upgrading with Electron Reservoirs 21
Coupled s-p-d Exchange in Facet-Controlled Pd3Pb Tripods Enhances Oxygen Reduction Catalysis 21
Photodeposited Amorphous Oxide Films for Electrochromic Windows 20
Direct Methane Conversion under Mild Condition by Thermo Electro or Photocatalysis 20
Supramolecular Chemistry of Anionic Dimers, Trimers, Tetramers, and Clusters 20
A Tailor-Made Interpenetrated MOF with Exceptional Carbon-Capture Performance from Flue Gas 20
Dynamic Disorder Dominates Delocalization, Transport, and Recombination in Halide Perovskites 20
Room-Temperature Aluminum-Sulfur Batteries with a Lithium-Ion-Mediated Ionic Liquid Electrolyte 20
Syntheses and Applications of Noble-Metal-free CeO2-Based Mixed-Oxide Nanocatalysts 20
Dipole-Dipole Interaction Management for Efficient Blue Thermally Activated Delayed Fluorescence Diodes 20
Electrostatic Stabilization of Single-Atom Catalysts by Ionic Liquids 20
Ordered-Vacancy-Induced Cation Intercalation into Layered Double Hydroxides: A General Approach for High-Performance Supercapacitors 20
Developments and Perspectives on Emerging High-Energy-Density Sodium-Metal Batteries 20
Efficient and Selective CO2 Reduction Integrated with Organic Synthesis by Solar Energy 20
The Versatility of Squaramides: From Supramolecular Chemistry to Chemical Biology 20
Turn-On Supramolecular Host-Guest Nanosystems as Theranostics for Cancer 20
Photoredox-Catalysis-Modulated, Nickel-Catalyzed Divergent Difunctionalization of Ethylene 19
Visualization of Anisotropic and Stepwise Piezofluorochromism in an MOF Single Crystal 19
Enantioselective Carbon-Carbon Bond Cleavage for Biaryl Atropisomers Synthesis 19
Understanding the Effect of Local Short-Range Ordering on Lithium Diffusion in Li1.3Nb0.3Mn0.4O2 Single-Crystal Cathode 19
Copper-Catalyzed Late-Stage Benzylic C(sp(3))-H Trifluoromethylation 18
Metal-Organic Framework Anchored with a Lewis Pair as a New Paradigm for Catalysis 18
Biomimetic Carbon Tube Aerogel Enables Super-Elasticity and Thermal Insulation 18
Photochromic 2D Metal-Organic Framework Nanosheets (MONs): Design, Synthesis, and Functional MON-Ormosil Composite 17
Cathodically Stable Li-O-2 Battery Operations Using Water-in-Salt Electrolyte 17
Boosting Fluorescence-Photoacoustic-Raman Properties in One Fluorophore for Precise Cancer Surgery 17
Defect Engineering in 2D Perovskite by Mn(II) Doping for Light-Emitting Applications 17
Unified Mechanistic Understandings of Pictet-Spengler Reactions 17
Merging Photoredox PCET with Ni-Catalyzed Cross-Coupling: Cascade Amidoarylation of Unactivated Olefins 17
A Structural Mimic of Carbonic Anhydrase in a Metal-Organic Framework 17
Activating p-Blocking Centers in Perovskite for Efficient Water Splitting 17
Molecular-Level Insight into How Hydroxyl Groups Boost Catalytic Activity in CO2 Hydrogenation into Methanol 17
Copper-Catalyzed Highly Enantioselective Difluoroalkylation of Secondary Propargyl Sulfonates with Difluoroenoxysilanes 17
Remote Control of Chemistry in Optical Cavities 17
Temperature-Controlled Evolution of Nanoporous MOF Crystallites into Hierarchically Porous Superstructures 17
Exploration of Syntheses and Functions of Higher Ladder-type pi-Conjugated Heteroacenes 17
Visualizing Battery Reactions and Processes by Using In Situ and In Operando Microscopies 17
Macrocyclic Polyradicaloids with Unusual Super-ring Structure and Global Aromaticity 16
Asymmetric Three-Component Reaction for the Synthesis of Tetrasubstituted Allenoates via Allenoate-Copper Intermediates 16
TiO2 on Gold Nanostars Enhances Photocatalytic Water Reduction in the Near-Infrared Regime 16
Ultra-fast NH4+ Storage: Strong H Bonding between NH4+ and Bi-layered V2O5 16
Doubly Orthogonal Labeling of Peptides and Proteins 16
Catalytic Regio- and Enantioselective Proton Migration from Skipped Enynes to Allenes 15
Determinants of Ion-Transporter Cancer Cell Death 15
Activating Aromatic Rings as Na-Ion Storage Sites to Achieve High Capacity 15
Site-Selective C-H Functionalization of (Hetero)Arenes via Transient, Non-symmetric lodanes 15
Palladium-Catalyzed Late-Stage Direct Arene Cyanation 14
Spin-Allowed Transitions Control the Formation of Triplet Excited States in Orthogonal Donor-Acceptor Dyads 14
Highly Concentrated Phthalimide-Based Anolytes for Organic Redox Flow Batteries with Enhanced Reversibility 14
Ti Substitution Facilitating Oxygen Oxidation in Na2/3Mg1/3Ti1/6Mn1/2O2 Cathode 14
Chiral Piperidines from Acyclic Amines via Enantioselective, Radical-Mediated delta C-H Cyanation 14
Phorbiplatin, a Highly Potent Pt(IV) Antitumor Prodrug That Can Be Controllably Activated by Red Light 14
Rational Design of Organic Probes for Turn-On Two-Photon Excited Fluorescence Imaging and Photodynamic Therapy 14
The Electronic Structure of Lutein 2 Is Optimized for Light Harvesting in Plants 14
Understanding the Bound Triplet-Pair State in Singlet Fission 14
alpha-Quaternary Chiral Aldehydes from Styrenes, Allylic Alcohols, and Syngas via Multi-catalyst Relay Catalysis 13
Enabling Graphene-Oxide-Based Membranes for Large-Scale Energy Storage by Controlling Hydrophilic Microstructures 13
RNA Splicing Analysis: From In Vitro Testing to Single-Cell Imaging 13
Light-Driven Chiral Switching of Supramolecular Metallacycles with Photoreversibility 13
Gold-Catalyzed Oxidative Coupling of Alkynes toward the Synthesis of Cyclic Conjugated Diynes 13
Plasmon-Mediated Electron Injection from Au Nanorods into MoS2: Traditional versus Photoexcitation Mechanism 13
Barrier-free Interface Electron Transfer on PtFe-Fe2C Janus-like Nanoparticles Boosts Oxygen Catalysis 13
Fluorinated Bambusurils as Highly Effective and Selective Transmembrane Cl-/HCO3- Antiporters 13
Controllable Chemical Vapor Deposition Growth of Two-Dimensional Heterostructures 13
Fluorescent Probes for Nanoscopic Imaging of Mitochondria 13
Plasmonic Sensing and Control of Single-Nanoparticle Electrochemistry 13
Stabilizing Cathode Materials of Lithium-Ion Batteries by Controlling Interstitial Sites on the Surface 13
Mesoionic Carbene (MIC)-Catalyzed H/D Exchange at Formyl Groups 12
Using Evolutionary Algorithms and Machine Learning to Explore Sequence Space for the Discovery of Antimicrobial Peptides 12
Size-Tunable Assemblies Based on Ferrocene-Containing DNA Polymers for Spatially Uniform Penetration 12
Bulk Contributions Modulate the Sum-Frequency Generation Spectra of Water on Model Sea-Spray Aerosols 12
Direct Dearomatization of Pyridines via an Energy-Transfer-Catalyzed Intramolecular [4+2] Cycloaddition 12
Capturing the Quenching Mechanism of Light-Harvesting Complexes of Plants by Zooming in on the Ensemble 12
Catalytic Non-redox Carbon Dioxide Fixation in Cyclic Carbonates 12
Tetraurea Macrocycles: Aggregation-Driven Binding of Chloride in Aqueous Solutions 12
Dissolution-Induced Surface Roughening and Oxygen Evolution Electrocatalysis of Alkaline-Earth Iridates in Acid 12
Multivariable Sieving and Hierarchical Recognition for Organic Toxics in Nonhomogeneous Channel of MOFs 12
Seven-Layered 2D Hybrid Lead Iodide Perovskites 12
An Auxiliary Approach for the Stereoselective Synthesis of Topologically Chiral Catenanes 12
Mesoporous TiO2 Microspheres with Precisely Controlled Crystallites and Architectures 12
Precise Placement of Single Monomer Units in Living Ring-Opening Metathesis Polymerization 11
A Practical and Stereoselective In Situ NHC-Cobalt Catalytic System for Hydrogenation of Ketones and Aldehydes 11
Novel Insights and Perspectives into Weakly Coupled ReS2 toward Emerging Applications 11
High-Speed Imaging Meets Single-Cell Analysis 11
A Massively Parallel Selection of Small Molecule-RNA Motif Binding Partners Informs Design of an Antiviral from Sequence 11
Dinitrogen Coupling to a Terpyridine-Molybdenum Chromophore Is Switched on by Fermi Resonance 11
Molecular Spectroscopic Characterization of Membrane Fouling: A Critical Review 11
High-Performance UV Enhancer Molecules Coupled with Photosynthetic Proteins for Ultra-Low-Intensity UV Detection 11
Evidence of Spiro-OMeTAD De-doping by tert-Butylpyridine Additive in Hole-Transporting Layers for Perovskite Solar Cells 11
Crystal Engineering of Organic Optoelectronic Materials 11
Dual Interphase Layers In Situ Formed on a Manganese-Based Oxide Cathode Enable Stable Potassium Storage 11
Controllable Growth of (n, n - 1) Family of Semiconducting Carbon Nanotubes 11
Longest C-C Single Bond among Neutral Hydrocarbons with a Bond Length beyond 1.8 angstrom 10
Selective Production of Diethyl Maleate via Oxidative Cleavage of Lignin Aromatic Unit 10