| General synthesis and definitive structural identification of MN4C4 single-atom catalysts with tunable electrocatalytic activities |
256 |
| A universal principle for a rational design of single-atom electrocatalysts |
216 |
| Single platinum atoms immobilized on an MXene as an efficient catalyst for the hydrogen evolution reaction |
208 |
| Atomically dispersed manganese catalysts for oxygen reduction in proton-exchange membrane fuel cells |
206 |
| Fe-N-C electrocatalyst with dense active sites and efficient mass transport for high-performance proton exchange membrane fuel cells |
189 |
| Catalysts for nitrogen reduction to ammonia |
172 |
| Direct transformation of bulk copper into copper single sites via emitting and trapping of atoms |
170 |
| Challenges and prospects in the catalysis of electroreduction of nitrogen to ammonia |
163 |
| High-efficiency oxygen reduction to hydrogen peroxide catalysed by oxidized carbon materials |
149 |
| Reaction systems for solar hydrogen production via water splitting with particulate semiconductor photocatalysts |
141 |
| Catalyst electro-redeposition controls morphology and oxidation state for selective carbon dioxide reduction |
130 |
| Bridging homogeneous and heterogeneous catalysis by heterogeneous single-metal-site catalysts |
127 |
| Promoting nitrogen electroreduction to ammonia with bismuth nanocrystals and potassium cations in water |
123 |
| Identification of single-atom active sites in carbon-based cobalt catalysts during electrocatalytic hydrogen evolution |
123 |
| Rational catalyst and electrolyte design for CO2 electroreduction towards multicarbon products |
121 |
| Achievements, challenges and perspectives on cathode catalysts in proton exchange membrane fuel cells for transportation |
114 |
| Metal ion cycling of Cu foil for selective C-C coupling in electrochemical CO2 reduction |
113 |
| Designing materials for electrochemical carbon dioxide recycling |
107 |
| Engineering the electronic structure of single atom Ru sites via compressive strain boosts acidic water oxidation electrocatalysis |
106 |
| Catalytic conversion of solar to chemical energy on plasmonic metal nanostructures |
104 |
| Steering post-C-C coupling selectivity enables high efficiency electroreduction of carbon dioxide to multi-carbon alcohols |
100 |
| Boosting the performance of Cu2O photocathodes for unassisted solar water splitting devices |
96 |
| Characteristics and performance of two-dimensional materials for electrocatalysis |
95 |
| Efficient hydrogen peroxide generation using reduced graphene oxide-based oxygen reduction electrocatalysts |
92 |
| Control of metal-support interactions in heterogeneous catalysts to enhance activity and selectivity |
92 |
| Iron-facilitated dynamic active-site generation on spinel CoAl2O4 with self-termination of surface reconstruction for water oxidation |
91 |
| Active learning across intermetallics to guide discovery of electrocatalysts for CO2 reduction and H-2 evolution |
89 |
| Understanding heterogeneous electrocatalytic carbon dioxide reduction through operando techniques |
89 |
| Biocatalytic cascades driven by enzymes encapsulated in metal-organic framework nanoparticles |
81 |
| Theory-guided Sn/Cu alloying for efficient CO2 electroreduction at low overpotentials |
81 |
| Opportunities and challenges for combining chemo- and biocatalysis |
77 |
| Single-atom tailoring of platinum nanocatalysts for high-performance multifunctional electrocatalysis |
76 |
| High-rate electroreduction of carbon monoxide to multi-carbon products |
75 |
| A comprehensive metabolic map for production of bio-based chemicals |
74 |
| Identification of active sites for acidic oxygen reduction on carbon catalysts with and without nitrogen doping |
73 |
| Recent trends and fundamental insights in the methanol-to-hydrocarbons process |
72 |
| Solar energy-driven lignin-first approach to full utilization of lignocellulosic biomass under mild conditions |
72 |
| Technical photosynthesis involving CO2 electrolysis and fermentation |
72 |
| Improved CO2 reduction activity towards C2+ alcohols on a tandem gold on copper electrocatalyst |
70 |
| Unified structural motifs of the catalytically active state of Co(oxyhydr)oxides during the electrochemical oxygen evolution reaction |
68 |
| A unique oxygen ligand environment facilitates water oxidation in hole-doped IrNiOx core-shell electrocatalysts |
67 |
| Encapsulating highly catalytically active metal nanoclusters inside porous organic cages |
64 |
| An atomic-scale view of single-site Pt catalysis for low-temperature CO oxidation |
64 |
| The stability number as a metric for electrocatalyst stability benchmarking |
64 |
| Chemically and electrochemically catalysed conversion of CO2 to CO with follow-up utilization to value-added chemicals |
63 |
| Overall water splitting by Ta3N5 nanorod single crystals grown on the edges of KTaO3 particles |
63 |
| Impact of nanoparticle size and lattice oxygen on water oxidation on NiFeOxHy |
59 |
| Structure of the catalytically active copper-ceria interfacial perimeter |
59 |
| Integrated tuneable synthesis of liquid fuels via Fischer-Tropsch technology |
57 |
| Copper nanocavities confine intermediates for efficient electrosynthesis of C3 alcohol fuels from carbon monoxide |
56 |
| Complete lignocellulose conversion with integrated catalyst recycling yielding valuable aromatics and fuels |
56 |
| Identification of the active complex for CO oxidation over single-atom Ir-on-MgAl2O4 catalysts |
55 |
| Unravelling structure sensitivity in CO2 hydrogenation over nickel |
52 |
| Decarboxylative C(sp(3))-N cross-coupling via synergetic photoredox and copper catalysis |
51 |
| Overcoming ammonia synthesis scaling relations with plasma-enabled catalysis |
50 |
| Net reduction of CO2 via its thermocatalytic and electrocatalytic transformation reactions in standard and hybrid processes |
50 |
| Efficient electrocatalytic CO2 reduction on a three-phase interface |
50 |
| Water oxidation on a mononuclear manganese heterogeneous catalyst |
49 |
| Two-dimensional copper nanosheets for electrochemical reduction of carbon monoxide to acetate |
49 |
| Towards dense single-atom catalysts for future automotive applications |
48 |
| Sinter-resistant metal nanoparticle catalysts achieved by immobilization within zeolite crystals via seed-directed growth |
48 |
| Highly selective oxidation of methane to methanol at ambient conditions by titanium dioxide-supported iron species |
47 |
| The renaissance of the Sabatier reaction and its applications on Earth and in space |
46 |
| A photochromic composite with enhanced carrier separation for the photocatalytic activation of benzylic C-H bonds in toluene |
44 |
| Selective aerobic oxidation reactions using a combination of photocatalytic water oxidation and enzymatic oxyfunctionalizations |
42 |
| Interaction trends between single metal atoms and oxide supports identified with density functional theory and statistical learning |
41 |
| Solvent-enabled control of reactivity for liquid-phase reactions of biomass-derived compounds |
41 |
| Evidence for product-specific active sites on oxide-derived Cu catalysts for electrochemical CO2 reduction |
41 |
| Time-resolved copper speciation during selective catalytic reduction of NO on Cu-SSZ-13 |
39 |
| Bimetallic synergy in cobalt-palladium nanocatalysts for CO oxidation |
38 |
| A green chemistry perspective on catalytic amide bond formation |
38 |
| Lithiation-induced amorphization of Pd3P2S8 for highly efficient hydrogen evolution |
38 |
| How strain can break the scaling relations of catalysis |
38 |
| Asymmetric formation of gamma-lactams via C-H amidation enabled by chiral hydrogen-bond-donor catalysts |
37 |
| Catalytic chemoselective functionalization of methane in a metal-organic framework |
35 |
| Strategies to break linear scaling relationships |
35 |
| Ternary intermetallic LaCoSi as a catalyst for N-2 activation |
34 |
| Reactive metal-support interactions at moderate temperature in two-dimensional niobium-carbide-supported platinum catalysts |
34 |
| Efficient electrocatalytic conversion of carbon monoxide to propanol using fragmented copper |
34 |
| Photoelectrocatalytic arene C-H amination |
33 |
| Cooperative copper centres in a metal-organic framework for selective conversion of CO2 to ethanol |
33 |
| Identifying the key obstacle in photocatalytic oxygen evolution on rutile TiO2 |
32 |
| Misconceptions and challenges in methane-to-methanol over transition-metal-exchanged zeolites |
30 |
| Imine hydrogenation with simple alkaline earth metal catalysts |
29 |
| Sustaining metal-organic frameworks for water-gas shift catalysis by non-thermal plasma |
29 |
| Catalyst deactivation via decomposition into single atoms and the role of metal loading |
29 |
| Cancer-derived exosomes loaded with ultrathin palladium nanosheets for targeted bioorthogonal catalysis |
29 |
| A high-energy-density and long-life lithium-ion battery via reversible oxide-peroxide conversion |
28 |
| General synthesis of primary amines via reductive amination employing a reusable nickel catalyst |
27 |
| Electricity-driven asymmetric Lewis acid catalysis |
26 |
| Operando NAP-XPS unveils differences in MoO3 and Mo2C during hydrodeoxygenation |
26 |
| Highly efficient organic photocatalysts discovered via a computer-aided-design strategy for visible-light-driven atom transfer radical polymerization |
26 |
| Cu2O nanocubes with mixed oxidation-state facets for (photo)catalytic hydrogenation of carbon dioxide |
25 |
| Asymmetric construction of atropisomeric biaryls via a redox neutral cross-coupling strategy |
24 |
| Catalytic CO2 reduction by palladium-decorated silicon-hydride nanosheets |
24 |
| Self-sustaining closed-loop multienzyme-mediated conversion of amines into alcohols in continuous reactions |
24 |
| Capture and characterization of a reactive haem-carbenoid complex in an artificial metalloenzyme |
24 |
| Ligand-enabled site-selectivity in a versatile rhodium(II)-catalysed aryl C-H carboxylation with CO2 |
23 |
| Electrochemically converting carbon monoxide to liquid fuels by directing selectivity with electrode surface area |
23 |
| Highly active enzyme-metal nanohybrids synthesized in protein-polymer conjugates |
23 |
| Tuning of catalytic sites in Pt/TiO2 catalysts for the chemoselective hydrogenation of 3-nitrostyrene |
23 |
| A multicomponent synthesis of stereodefined olefins via nickel catalysis and single electron/triplet energy transfer |
22 |
| Solar-driven reduction of aqueous CO2 with a cobalt bis(terpyridine)-based photocathode |
22 |
| Electrocatalytic transformation of HF impurity to H-2 and LiF in lithium-ion batteries |
22 |
| Chiral synthesis of LSD1 inhibitor GSK2879552 enabled by directed evolution of an imine reductase |
22 |
| Constraining CO coverage on copper promotes high-efficiency ethylene electroproduction |
22 |
| Foundations and strategies of the construction of hybrid catalysts for optimized performances |
22 |
| A bioinspired soluble manganese cluster as a water oxidation electrocatalyst with low overpotential |
22 |
| Solvent-mediated charge separation drives alternative hydrogenation path of furanics in liquid water |
21 |
| Computational optimization of electric fields for better catalysis design |
21 |
| First-principles-based multiscale modelling of heterogeneous catalysis |
21 |
| Progress and outlook for solid oxide fuel cells for transportation applications |
20 |
| Selectivity control of CO versus HCOO- production in the visible-light-driven catalytic reduction of CO2 with two cooperative metal sites |
20 |
| A photoswitchable catalyst system for remote-controlled (co)polymerization in situ |
20 |
| Photocatalytic regio- and stereoselective C(sp(3))-H functionalization of benzylic and allylic hydrocarbons as well as unactivated alkanes |
20 |
| Making quantitative sense of electromicrobial production |
19 |
| Non-proteinaceous hydrolase comprised of a phenylalanine metallo-supramolecular amyloid-like structure |
19 |
| Tandem copper hydride-Lewis pair catalysed reduction of carbon dioxide into formate with dihydrogen |
19 |
| Atomic-scale insights into surface species of electrocatalysts in three dimensions |
19 |
| alpha-Branched amines by catalytic 1-addition of C-H bonds and aminating agents to terminal alkenes |
19 |
| Carbon monoxide electroreduction as an emerging platform for carbon utilization |
19 |
| Redox tuning the Weakley-type polyoxometalate archetype for the oxygen evolution reaction |
19 |
| Engineering highly functional thermostable proteins using ancestral sequence reconstruction |
18 |
| Rapid virtual screening of enantioselective catalysts using CatVS |
18 |
| A silver catalyst activated by stacking faults for the hydrogen evolution reaction |
18 |
| Structural principles to steer the selectivity of the electrocatalytic reduction of aliphatic ketones on platinum |
18 |
| Bracing copper for the catalytic oxidation of C-H bonds |
18 |
| Highly tunable multi-borylation of gem-difluoroalkenes via copper catalysis |
17 |
| Sesquiterpene cyclizations catalysed inside the resorcinarene capsule and application in the short synthesis of isolongifolene and isolongifolenone |
17 |
| Iron-catalysed substrate-directed Suzuki biaryl cross-coupling |
17 |
| Ultrahigh-throughput screening enables efficient single-round oxidase remodelling |
17 |
| Palladium-catalysed C-H glycosylation for synthesis of C-aryl glycosides |
17 |
| Gasoline automobile catalysis and its historical journey to cleaner air |
17 |
| Rational design, enantioselective synthesis and catalytic applications of axially chiral EBINOLs |
17 |
| A family of native amine dehydrogenases for the asymmetric reductive amination of ketones |
16 |
| Ethylene glycol as an efficient and reversible liquid-organic hydrogen carrier |
16 |
| Pentamethylcyclopentadienyl rhodium(III)-chiral disulfonate hybrid catalysis for enantioselective C-H bond functionalization |
16 |
| Perfluorocarbon nanoemulsion promotes the delivery of reducing equivalents for electricity-driven microbial CO2 reduction |
15 |
| Tetrasubstituted allenes via the palladium-catalysed kinetic resolution of propargylic alcohols using a supporting ligand |
15 |
| Magnetic field remotely controlled selective biocatalysis |
15 |
| S-adenosylhomocysteine as a methyl transfer catalyst in biocatalytic methylation reactions |
15 |
| Complete electron economy by pairing electrolysis with hydrogenation |
15 |
| Dynamic coordination of cations and catalytic selectivity on zinc-chromium oxide alloys during syngas conversion |
15 |
| Deciphering key intermediates in the transformation of carbon dioxide into heterocyclic products |
14 |
| Atroposelective synthesis of tetra-ortho-substituted biaryls by catalyst-controlled non-canonical polyketide cyclizations |
14 |
| Direct catalytic transformation of white phosphorus into arylphosphines and phosphonium salts |
14 |
| Synthesis of reaction-adapted zeolites as methanol-to-olefins catalysts with mimics of reaction intermediates as organic structure-directing agents |
14 |
| Homocoupling-free iron-catalysed twofold C-H activation/cross-couplings of aromatics via transient connection of reactants |
14 |
| In situ quantitative single-molecule study of dynamic catalytic processes in nanoconfinement |
14 |
| Solvent-determined mechanistic pathways in zeolite-H-BEA-catalysed phenol alkylation |
14 |
| Operando monitoring of temperature and active species at the single catalyst particle level |
14 |
| Redox-switchable siderophore anchor enables reversible artificial metalloenzyme assembly |
14 |
| Structural selectivity of supported Pd nanoparticles for catalytic NH3 oxidation resolved using combined operando spectroscopy |
13 |
| Highly branched polyethylene oligomers via group IV-catalysed polymerization in very nonpolar media |
13 |
| Fundamentals of C-O bond activation on metal oxide catalysts |
13 |
| Streamlined hydrogen production from biomass |
13 |
| Extending the limits of Pt/C catalysts with passivation-gas-incorporated atomic layer deposition |
13 |
| Transition state and product diffusion control by polymer-nanocrystal hybrid catalysts |
13 |
| Complex dynamics in a two-enzyme reaction network with substrate competition |
13 |
| Biocompatibility and therapeutic potential of glycosylated albumin artificial metalloenzymes |
12 |
| Growing highly pure semiconducting carbon nanotubes by electrotwisting the helicity |
12 |
| Control of interfacial acid-metal catalysis with organic monolayers |
12 |
| Enantioselective dearomative prenylation of indole derivatives |
12 |
| Engineered enzymes that retain and regenerate their cofactors enable continuous-flow biocatalysis |
12 |
| Selective and synergistic cobalt(III)-catalysed three-component C-H bond addition to dienes and aldehydes |
12 |
| Lifetime improvement in methanol-to-olefins catalysis over chabazite materials by high-pressure H-2 co-feeds |
12 |
| Detection of catalytic intermediates at an electrode surface during carbon dioxide reduction by an earth-abundant catalyst |
11 |
| Versatile and robust C-C activation by chelation-assisted manganese catalysis |
11 |
| Intrinsically stable in situ generated electrocatalyst for long-term oxidation of acidic water at up to 80 degrees C |
11 |
| Organosodium compounds for catalytic cross-coupling |
11 |
| Dual-catalytic transition metal systems for functionalization of unreactive sites of molecules |
11 |
| Practical synthesis of C1 deuterated aldehydes enabled by NHC catalysis |
11 |
| Efficient reductive desymmetrization of bulky 3-cyclodiketones enabled by structure-guided directed evolution of a carbonyl reductase |
11 |
| A robust and precious metal-free high performance cobalt Fischer-Tropsch catalyst |
11 |
| The atomic-resolution crystal structure of activated [Fe]-hydrogenase |
10 |
| The emergence of Pd-mediated reversible oxidative addition in cross coupling, carbohalogenation and carbonylation reactions |
10 |
| Selecting between two transition states by which water oxidation intermediates decay on an oxide surface |
10 |
| The active sites of a working Fischer-Tropsch catalyst revealed by operando scanning tunnelling microscopy |
10 |
| Branched aldehydes as linchpins for the enantioselective and stereodivergent synthesis of 3-aminoalcohols featuring a quaternary stereocentre |
9 |
| Evidence of radical chemistry in catalytic methane oxybromination |
9 |
| Prebiotic iron-sulfur peptide catalysts generate a pH gradient across model membranes of late protocells |
9 |
| Direct electrosynthesis of sodium hydroxide and hydrochloric acid from brine streams |
9 |
| Molecular nitrogen promotes catalytic hydrodeoxygenation |
9 |
| Rational design of selective metal catalysts for alcohol amination with ammonia |
9 |
| Carboxyl intermediate formation via an in situ-generated metastable active site during water-gas shift catalysis |
9 |
| Regiodivergent enantioselective C-H functionalization of Boc-3-oxazinanes for the synthesis of beta(2)- and beta(3)-amino acids |
8 |
| Tunable catalyst-controlled syntheses of beta- and gamma-amino alcohols enabled by silver-catalysed nitrene transfer |
8 |
| Mapping out the key carbon-carbon bond-forming steps in Mn-catalysed C-H functionalization |
8 |
| Chemoenzymatic asymmetric synthesis of the metallo-beta-lactamase inhibitor aspergillomarasmine A and related aminocarboxylic acids |
7 |
| Catalyst as colour indicator for endpoint detection to enable selective alkyne trans-hydrogenation with ethanol |
7 |
| Remarkable improvement in low temperature performance of model three-way catalysts through solution atomic layer deposition |
7 |
| The highly surprising behaviour of diphosphine ligands in iron-catalysed Negishi cross-coupling |
6 |
| Probing the transition state in enzyme catalysis by high-pressure NMR dynamics |
6 |
| Crossing the great divide between single-crystal reactivity and actual catalyst selectivity with pressure transients |
6 |
| Metabolic engineering of Escherichia coli for secretory production of free haem |
6 |
| Catalytic hydrogen atom transfer from hydrosilanes to vinylarenes for hydrosilylation and polymerization |
5 |
| SmI2-catalysed cyclization cascades by radical relay |
5 |
| A Rieske oxygenase/epoxide hydrolase-catalysed reaction cascade creates oxygen heterocycles in mupirocin biosynthesis |
5 |
| Electrophilic aromatic substitution over zeolites generates Wheland-type reaction intermediates |
5 |
| Development of heterogeneous catalyst systems for the continuous synthesis of chiral amines via asymmetric hydrogenation |
5 |
